Search results for " Photoreactor"

C3N4 for CO2 photoreduction: catalyst performance and stability in batch and continuous reactor

2019

In this study, various C3N4 samples were prepared and characterized. CO2 photoreduction was carried out by using C3N4 as powder and coated on glass support in a batch reactor or embedded in a Nafion membrane in a continuous reactor

Photocatalytic membrane reactors

2008

Validation of a two-dimensional modeling of an externally irradiated slurry photoreactor

2015

Abstract A two-dimensional model describing the behavior of a batch cylindrical photoreactor has been validated through a series of photocatalytic reactivity runs. The light intensity radiation field produced by 1–6 external UV fluorescent lamps was modeled together with Langmuir–Hinshelwood kinetics and 4-nitrophenol (NP) and Degussa P25 TiO 2 were used as the probe molecule and the catalyst, respectively. The experiments were carried out under different conditions of light intensity, photocatalyst amount and substrate concentration. The model parameters were the kinetic constant of substrate adsorption, desorption and degradation and the exponent of the power law expressing the kinetics d…

Estimating radiant fields in flat heterogeneous photoreactors by the six-flux model

2006

Heterogeneous photoreactor modeling is a task complicated by the integro-differential nature of the Radiation Transfer Equation (RTE) when scattering phenomena are important. In the present work, a novel “Six Flux Model” (SFM) is proposed, which may be regarded as a step forward with respect to the previously proposed “Two Flux Model” (TFM). In order to validate the newly proposed model, Monte Carlo simulations of an indefinite plane-slab photoreactor have been performed. As no simplifying assumptions are involved in this case, the information obtained may be regarded as “pseudo-experimental,” and therefore compared with the predictions of both TFM and SFM models. Results show that the nove…

Two-Dimensional Modeling of an Externally Irradiated Slurry Photoreactor

2013

Abstract A batch cylindrical photocatalytic reactor, externally irradiated by 1–6 UV fluorescent lamps and containing a stirred slurry of polycrystalline TiO2, was modeled by coupling a modified Langmuir–Hinshelwood kinetics together with a two-dimensional light intensity field. The radiation field has been determined on the main assumptions of diffuse radiation, isotropic scattering and negligible backward reflected photon flow. The model has been applied to the photocatalytic oxidation of organic substrates which do not undergo homogeneous photochemical degradation. The model is characterized by the following four parameters: the kinetic constants of substrate adsorption, desorption and d…

Photocatalytic degradation of 4-nitrophenol in a continuous reactor containing titanium dioxide supported on glass beads

2008

WOS: 000258975200009

Quasi-isoactinic reactor for photocatalytic kinetics studies

2007

Photochemical reactors characterized by almost uniform values of the local volumetric rate of photon absorption (LVRPA), i.e., quasi-isoactinic photoreactors, are particularly suitable for assessing the influence of radiant field intensity in kinetic studies. In this work, Monte Carlo simulations have been performed to obtain LVRPA values in a flat photoreactor irradiated on both sides. This configuration appears to be particularly suitable for obtaining quasi-isoactinic conditions. The influence of catalyst albedo and scattering phase function is assessed, and the conditions for obtaining iso-actinicity are discussed. Finally, these conditions are related to an easy-to-measure parameter, n…

Kinetics of 4-Methoxybenzyl Alcohol Oxidation in Aqueous Solution in a Fixed Bed Photocatalytic Reactor

2010

WOS: 000280384800004

Carbon Nitride-Based Catalysts for High Pressure CO2 Photoreduction

2022

In the current research, the productivity of CO2 photoreduction has been boosted by performing the reaction in an innovative photocatalytic reactor, which allows for operation up to 20 bar. A set of photocatalysts were used, including three types of pristine TiO2, i.e., one commercially prepared (Evonik P25), one home-prepared by flame spray pyrolysis (FSP), and one obtained by the hydrolysis of TiCl4 (TiO2exCl), a bare thermo-exfoliated carbon nitride (C3N4-TE), and binary materials composed of TiO2 and C3N4-TE. The photoreduction was carried out in water at pH 14 and in the presence of Na2SO3 as a hole scavenger. Hydrogen and very small amounts of CO were detected in the head space of the…